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71.
In active landslides, the prediction of acceleration of movement is a crucial issue for the design and performance of warning systems. The landslide of Vallcebre in the Eastern Pyreenes, Spain, has been monitored since 1996 and data on rainfall, groundwater levels and ground displacements are measured on a regular basis. Displacements observed in borehole wire extensometers have shown an immediate response of the landslide to rainfall episodes. This rapid response is likely due to the presence of preferential drainage ways. The occurrence of nearly constant rates of displacement in coincidence with steady groundwater levels suggests the presence of viscous forces developed during the movement. An attempt to predict both landslide displacements and velocities was performed at Vallcebre by solving the momentum equation in which a viscous term (Bingham and power law) was added. Results show that, using similar rheological parameters for the entire landslide, computed displacements reproduce quite accurately the displacements observed at three selected wire extensometers. These results indicate that prediction of displacements from groundwater level changes is feasible.  相似文献   
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A methodological proposal for the assessment of impacts due to linear infrastructures such as motorways, railways, etc. is presented. The approach proposed includes a series of specific issues to be addressed for each geomorphological feature analysed—both ‘static’ and ‘dynamic’—as well as a series of steps to be followed in the process.Geomorphic characteristics potentially affected were initially identified on the basis of a conceptual activities/impacts model that helps to single out geomorphic impacts related to environmental concerns for the area. The following issues were addressed for each individual impact: nature of potential effects; indicators that can be used to measure impacts; criteria of ‘geomorphologic performance’; procedure for measurement/prediction of changes; translation of geomorphologic impacts into significant terms from the viewpoint of human concerns; possible mitigation and/or compensation measures.The procedure has been applied to a case study corresponding to a new motorway in the Basque Country, northern Spain. Geomorphological impacts considered in this analysis included: (1) consumable resources; (2) sites of geomorphological interest; (3) land units with high potential for use, high productivity or value for conservation; (4) visual landscape; (5) slope instability processes. The procedure has been designed for implementation in a Geographic Information System (GIS) environment. Details are given on the application of the method to each individual impact analysed and results are presented in both numerical and map form.Impacts assessed were initially expressed by means of heterogeneous magnitudes, depending on the geomorphological feature considered. Those geomorphological impacts were then translated into significant terms and homogeneous magnitudes. Integration was carried out on the basis of impact values thus obtained. Final integrated results were also expressed in numerical and map form.The method proposed enables comparison of alternatives as well as ‘prediction’ and assessment of impacts in terms directly related to geomorphic characteristics. It also facilitates the expression of those impacts in terms that allow integration with other types of environmental impacts.  相似文献   
74.
The analytical capabilities of laser ablation (LA)-ICP-MS in determining Li, Be and B at trace levels in geological samples have been tested on a series of glass reference materials and natural samples. The LA-ICP-MS instrument used consisted of a sector-field ICP-MS coupled with a laser ablation microprobe operating at either 266 or 213 nm wavelength. Reference glasses from NIST (SRM 612, 614 and 616) and MPI-DING (KL2-G, ML3B-G, StHs6/80-G, GOR128-G, GOR132-G, T1-G and ATHO-G) were selected to develop the analytical method and to assess the best instrumental configuration. A series of calcic amphiboles with different Li, Be and B concentrations were also analysed using both LA-ICP-MS and SIMS to test the applicability of the method to natural minerals. Results indicated that with a spot size of 40 μm the agreement between measured and reference values of Li, Be and B is generally better than 10% for NIST SRM 612 and 20% for NIST SRM 614. Average reproducibility at the 2s level was 10% for Li, 20% for Be and 15% for B. Limits of detection were approximately 100 ng g-1 for Be and B and 200 ng g-1 for Li. These results were confirmed by analyses carried out on natural amphiboles and compared well in terms of precision and accuracy with those commonly achieved by SIMS.  相似文献   
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SIMS analyses have been carried out on clinopyroxenes, plagioclases and amphiboles of six gabbroic samples from Holes 921–924 of the Ocean Drilling Program Leg 153 sited in the MARK area of the Mid-Atlantic Ridge at the ridge–transform intersection, to investigate the rare earth, trace and volatile element distribution in the lower ocean crust during igneous crystallization and higher grade metamorphic conditions. The metagabbros underwent granulite to subgreenschist facies conditions through three main tectono-metamorphic phases: (1) ductile regime (750 < T < 1000 °C and P ≈ 0.3 GPa); (2) transitional regime (600 < T < 700 °C and P ≈ 0.2 GPa); (3) brittle regime (350 ≤ T < 600 °C and P < 0.2 GPa). Igneous clinopyroxenes show C1-chondrite normalized patterns depleted in LREE, and nearly flat for HREE. The rare earth and trace element distributions in igneous clinopyroxenes and plagioclases indicate that these minerals act as REE reservoirs, and comprise the main contribution to the overall rock content. The abundances in igneous minerals reflect the degree of fractionation of the parent liquids. In metamorphic clinopyroxenes recrystallized in anhydrous assemblages, the REE and trace elements patterns mimic those of the primary ones. Conversely, clinopyroxene re-equilibrated in amphibole-bearing assemblages shows a significant increase in REE, Ti, Zr, Y and V, a negative Eu anomaly, and slight decreases in Sr and Ba. An overall increase of REE and some trace elements is evident in hydrous assemblages, with preferential partitioning in the amphibole. It shows high Ti (18196–22844 ppm), LREE depleted patterns and LaN/SmN=0.10–0.33, LaN/YbN=0.10–0.30. Amphiboles from granoblastic assemblages show homogeneous patterns with no or a positive anomaly for TiN and negative anomalies for SrN and ZrN. Volatiles in amphibole are low, with Cl/F < 1; H2O% is significantly lower than the stoichiometric ratio (1.33–1.53%). The composition of the clinopyroxene and amphibole recrystallized in low-strain domains records evidence of incomplete re-equilibration, and element diffusion and partitioning is in part controlled by the textural site. The possible origins of the fluids involved in the metamorphic recrystallization are discussed: (1) remobilization from igneous amphibole; (2) exsolution from evolved melts; (3) introduction of seawater-derived fluids modified in rock-dominated systems; (4) injection of highly evolved hydrous melts during the metamorphic process. Received: 6 September 1999 / Accepted: 6 March 2000  相似文献   
77.
Recent improvements in both Infra-red spectroscopy and equilibrator techniqueshave allowed to determine, for the first time, pCO2using simultaneously and continuously both the direct and indirect methods in an estuary where pCO2 values range from 500 to 8500 atm and salinity from 0 to 30. Our results show that both methods are in excellent agreement in the wholeestuary (r2 = 0.999, n = 1075, p < 0.0001). Thus, the NBS (US National Bureau of Standards) scale, although inadequate for seawater samples, is appropriate for estuarine waters and can be applied with confidence to calculate pCO2.  相似文献   
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79.
Modeling transport of contaminants in the earths subsurface relies on numerical solutions over grids with blocks larger than Darcys scale. The hydraulic conductivity is homogenized over the grid blocks and the plumes spreading is reduced as a consequence of the wiped-out variability. To compensate for this loss Rubin et al. (1999) proposed to augment mixing by block-effective dispersion coefficients, and Rubin et al. (2003) showed, by means of two dimensional simulations, how this concept can be applied in practice. In this paper, we present new solutions of the block-effective dispersion tensor for an axisymmetric exponential covariance model. In addition, we discuss the influence of pore-scale dispersion in both two- and three-dimensional applications.  相似文献   
80.
Three ice cores and a set of snow pit samples collected on James Ross Island, Antarctic Peninsula, in 1979, 1981 and 1991 have been analyzed for water stable isotope content D or 18O (isotopic temperature) and major chemical species. A reliable and detailed chronological scale has been established first for the upper 24.5 m of water equivalent (1990–1943) where various data sets can be compared, then extended down to 59.5 m of water equivalent (1847) with the aid of seasonal variations and the sulphate peak reflecting the 1883 Krakatoa volcanic eruption. At James Ross Island, sea-salt aerosol is generally produced by ice-free marine surfaces during the summer months, although some winter sea-salt events have been observed. For the upper part of the core (1990–1943), correlations (positive or negative) were calculated between isotopic temperature, chloride content (a sea-salt indicator), sea-ice extent, regional atmospheric temperature changes and atmospheric circulation. The D and chloride content correlation was then extended back to 1847, making it possible to estimate decadal sea-ice cover fluctuations over the study period. Our findings suggest that ice-core records from James Ross Island reflect the recent warming and sea-ice decrease trends observed in the Antarctic Peninsula area from the mid-1940s.  相似文献   
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